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21.
22.
《International Journal of Hydrogen Energy》2022,47(90):38114-38123
High-temperature water electrolysis through solid oxide electrolysis cells (SOEC) will play a key role in building a hydrogen economy in the future. However, the delamination between the air electrode and the electrolyte remains a critical issue to be addressed. Previously, it was hypothesized that Co migration may improve the catalytic activity of the SrZrO3 second phase at the LSCF-YSZ interface, eventually leading to the delamination. In this work, the LSCF-YSZ interfaces sintered at different temperatures were examined in detail. The activation behaviors of the LSCF electrodes upon application with electrolysis current were characterized under different conditions. Further, samples containing purposely added SrZrO3 interlayer with and without cobalt were fabricated and compared. The activation process is less significant for the sample with cobalt-added SrZrO3 interlayer than the sample with pure SrZrO3 layer, supporting the hypothesis that Co migration may lead to the activation behavior. 相似文献
23.
Peng Wang Yan Li Yujiao Qu Baowei Wang Jingxin Sun Chunwei Miao Ming Huang He Huang Congxiang Zhang 《International Journal of Food Science & Technology》2022,57(6):3428-3439
The effects of cellulose microfibres (CMFs, Average size: 100 ± 5 μm) and cellulose nanofibres (CNFs, Average size: 60 ± 3 nm) on the properties of myofibrillar protein (MP) gels from duck breast meat were studied. The results demonstrated that CMFs and CNFs were mostly connected to MP by non-covalent bonds, the diffusion and cross-linking of MP molecules was promoted, and a denser and more complete gel network was formed. With the increases of CMFs and CNFs concentration (0–10%), the hardness was increased by 13.15% and 19.78% for CMFs10% and CNFs10% gels, respectively, and the elasticity was increased by 40% and 80%, respectively. At the same concentration (0–10%), the increase in gel hardness, viscoelasticity and immobilised water content was greater in the CNFs-MP group than in the CMFs-MP group. The CNFs-MP group had a tighter gel network, and CNFs had a better potential to improve the gelation performance of MP. 相似文献
24.
Characteristics of reaction and product microstructure during light calcination of magnesite in transport bed 下载免费PDF全文
A gas-heating laboratory transport bed was adopted to simulate the industrial transportbed reactor for flash calcination of magnesite, and a method based on TG analysis of a reacted sample was further developed to calculate the decomposition rate or conversion of its containing MgCO3. The study investigated how the conversion and product reactivity as well as microstructure vary with reaction conditions including temperature, particle size and times of re-calcination for powder magnesite. Magnesite powder (<150 μm) calcination is a quick reaction that reaches 98% decomposition of its containing MgCO3 in 1—2 s,corroborating the feasibility of magnesite flash-calcination in transport bed reactors. The coloration time given by the citric acid chromogenic method was 17—55 s and 294 s for the obtained products from transport and fixed beds, respectively. This proves the obviously higher activity and thus improved microstructure of the product from transport bed. During the calcination process, the MgO grain size of the product gradually increases, and the surface structure changes from loose and porous to dense and smooth. This structural change can be completed within a few seconds. 相似文献
25.
以方竹笋中提取的膳食纤维为研究对象,采用动态高压微射流(dynamic high-pressure micro-fluidization, DHPM)在不同压力条件(0,50,100,150,200 MPa)下进行处理,探究其对竹笋膳食纤维(bamboo shoots dietary fiber, BSDF)理化和结构特性的影响。结果表明,随着处理压力的增大,BSDF粒径先增大后减小,当处理压力为150 MPa时,粒径最小,为(370±11) nm,此条件下BSDF的持水力、持油力和膨胀力达到最大,较对照组分别提高了47.74%,50.54%,61.27%,且差异显著(P<0.05)。红外光谱分析表明DHPM处理不会改变BSDF的官能团,但会使BSDF内部的部分氢键断裂和半纤维素、木质素等发生降解;X射线衍射和热重分析表明DHPM处理不会引起BSDF的晶体结构改变,但晶体有序度会下降,进而导致其热稳定性降低;微观结构分析显示DHPM处理会使BSDF颗粒尺寸减小、表面粗糙、组织松散,且当处理压力为200 MPa时,颗粒发生团聚。综上,DHPM可以有效改善BSDF的理化性质,在膳食纤维改性方面具有一定的应用价值。 相似文献
26.
Xu Wang Yujie Zhong Qian Sun Dongqing Qi Fuxue Yan Quangang Xian Dong Wang Kui Du Jingyang Wang 《Journal of the American Ceramic Society》2019,102(4):2176-2186
The microstructure evolution and growth behavior of the Al2O3/Y3Al5O12(YAG)/ZrO2 ternary eutectic ceramics during directional solidification were well investigated. During directional solidification of the Al2O3/YAG/ZrO2 ternary eutectic ceramics, {} Al2O3 paralleled with {001}ZrO2 while they did not parallel with {001}YAG at the same time in the competitive growth stage. All of the interfaces parallel to each other finally. The area percentage of the Al2O3/ZrO2 and YAG/ZrO2 interfaces are 40.4 ± 0.2% and 30.8 ± 0.1%, respectively, higher than that of the Al2O3/YAG (28.8 ± 0.2%). The content of Al2O3 and YAG phases are 39.9% and 41.1%, respectively, almost double of that of ZrO2. The interfaces of Al2O3/ZrO2 and YAG/ZrO2 are shorter and more dispersed than that of the Al2O3/YAG. It was found that the interfacial energy of Al2O3/ZrO2 and YAG/ZrO2 interfaces are lower than that of Al2O3/YAG. It can be concluded that interfacial energy plays a decisive role in affecting the crystallographic orientation and interfaces distribution in the Al2O3/YAG/ZrO2 eutectic since the interfaces of Al2O3/ZrO2 and YAG/ZrO2 with lower interfacial energy can be formed more easily during directional solidification. Therefore, the contents of Al2O3/ZrO2 and YAG/ZrO2 interfaces are higher. This study can provide theoretical guidance for interface design of multi-phase materials. 相似文献
27.
Farzad Saberi Fatemeh Kouhsari Samaneh Abbasi Cristina M. Rosell Mehdi Amini 《International Journal of Food Science & Technology》2021,56(12):6559-6571
The aim of the study was to evaluate the physical and microstructural characteristics of crackers baked in four different industrial baking ovens (indirect radiation-cyclotherm, indirect convection, hybrid and industrial tunnel-ITO). Indirect convection and cyclotherm ovens provide the highest (5685.43 ± 51 W m−2) and the lowest (4860 ± 38.87 W m−2) amount of heat flux, respectively. Despite the amount of heat flux, indirect convection led to crackers with the highest moisture (7.86% vs. 4.82% in clyclotherm) and specific volume, but the lowest hardness. Cyclotherm resulted in crackers with lower specific volume, surface area, porosity, smooth and regular surface. Conversely, the hybrid and ITO ovens showed closer heat flux, leading to crackers with similar moisture content, texture parameters, specific volume, browning and inner porosity. Overall results show the potential of baking using different ovens for modifying the quality parameters of the crackers. 相似文献
28.
《中国有色金属学会会刊》2021,31(9):2703-2715
The effects of joining temperature (TJ) and time (tJ) on microstructure of the transient liquid phase (TLP) bonding of GTD-111 superalloy were investigated. The bonding process was applied using BNi-3 filler at temperatures of 1080, 1120, and 1160 °C for isothermal solidification time of 195, 135, and 90 min, respectively. Homogenization heat treatment was also applied to all of the joints. The results show that intermetallic and eutectic compounds such as Ni-rich borides, Ni−B−Si ternary compound and eutectic-γ continuously are formed in the joint region during cooling. By increasing tJ, intermetallic phases are firstly reduced and eventually eliminated and isothermal solidification is completed as well. With the increase of the holding time at all of the three bonding temperatures, the thickness of the athermally solidified zone (ASZ) and the volume fraction of precipitates in the bonding area decrease and the width of the diffusion affected zone (DAZ) increases. Similar results are also obtained by increasing TJ from 1080 to 1160 °C at tJ=90 min. Furthermore, increasing the TJ from 1080 to 1160 °C leads to the faster elimination of intermetallic phases from the ASZ. However, these phases are again observed in the joint region at 1180 °C. It is observed that by increasing the bonding temperature, the bonding width and the rate of dissolution of the base metal increase. Based on these results, increasing the homogenization time from 180 to 300 min leads to the elimination of boride precipitates in the DAZ and a high uniformity of the concentration of alloying elements in the joint region and the base metal. 相似文献
29.
Jonas Stiller Daisy Nestler Husam Ahmad Erik Päßler Guntram Wagner Lothar Kroll 《International Journal of Applied Ceramic Technology》2021,18(2):280-288
The production of ceramic matrix composites (CMC) based on C/C-SiC is still very cost-intensive and therefore only economical for a few applications. The fabrication of the preforms involves many costs that need to be reduced. In this work, the shaping of the CFRP-preforms is realized by thermoset injection molding, which enables large-scale production. The polymeric matrix used is a multi-component matrix consisting of novolak resin, curing agent and lubricant. Six millimeter chopped carbon fiber with a proportion of 50 wt.% were used as a reinforcement. These ingredients are processed by an industrial equipment for compounding and injection molding in order to manufacture a CFRP demonstrator representing a brake disc. Test specimens are cut out of the demonstrator in different directions in order to investigate influences of flow direction and weld lines on microstructural and mechanical properties. Afterward, the CFRP samples were converted to C/C-SiC composites by the liquid silicon infiltration process. The article addresses the flow behavior of the compound during the injection molding and the building of the weld lines in the demonstrator. In addition, results of the directional dependence of the microstructural and mechanical properties within the fabricated disc in the different production steps are presented. 相似文献
30.